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set diffusion coefficient of different solutes in toughreact?

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As far as I know, only one solute diffusion coefficient can be set for the whole model,which is not practical.

Then how to set the diffusion coefficient of different solutes in different soil layer in toughreact?

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It is my understanding that the diffusion coefficient for all aqueous species is assumed to the be the same in TOUGHREACT.  You might contact the TOUGHREACT authors at LBL to see if they have any ideas or planned developments on how to deal with this limitation.

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